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Radiography: Radiation Physics

Radiography

Radiation is energy that moves from one place to another in a form that can be described as waves or particles. We are exposed to radiation in our everyday life.

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What is radiationTypesRadioactive decayHalf-lifeActivityAtomic structureSubatomic particlesZ, A and NAtomic modelsShells and energyIsotopesX-ray productionFormulas

What is radiation?

Everyday sources of radiation

Familiar sources include the sun, microwave ovens and car radios. Most of this radiation carries no risk to health, but some does. In general, radiation has lower risk at lower doses and higher risk at higher doses. Depending on the type, different measures protect our bodies and the environment while we benefit from its many applications.

Benefits of radiation

Types of radiation

Non-ionizing radiation

Non-ionizing radiation

Lower energy radiation that cannot detach electrons from atoms or molecules. Its energy can make molecules vibrate and produce heat, which is how microwave ovens work. For most people it is not a health risk, though workers in regular contact with some sources may need protection from heat. Radio waves and visible light are examples.

Ionizing radiation

Ionizing radiation

Radiation with enough energy to detach electrons from atoms or molecules, producing ions (charged atoms or molecules). In high doses it can damage cells or organs or even cause death. With correct use, doses and protection it has many beneficial uses in energy, industry, research and in diagnosing and treating diseases such as cancer.

Radioactive atoms and radioactive decay

Radioactive decay

Most atoms are stable thanks to a balanced mix of protons and neutrons in the nucleus. In unstable atoms the mix cannot hold together. These are radioactive atoms, and when they decay they release ionizing radiation: alpha particles, beta particles, gamma rays or neutrons.

Alpha radiation

Alpha decay
Alpha radiation

Heavy, positively charged particles (a helium-4 nucleus). They cannot penetrate skin and are stopped by a sheet of paper. If alpha emitters are breathed in, eaten or drunk, they can expose internal tissue directly. Americium-241 is an alpha emitter used in smoke detectors.

AZX → A−4Z−2Y + 42He (α)

Beta radiation

Beta decay
Beta radiation penetration and applications

Beta particles are electrons, more penetrating than alpha: they pass through 1-2 cm of water and are stopped by a few millimetres of aluminium. Tritium (hydrogen-3) powers self-glowing emergency exit lights, and carbon-14 is used to date ancient objects.

Gamma rays

Gamma decay
Gamma radiation

Electromagnetic radiation similar to X-rays. Some pass through the body, others are absorbed and may cause damage. Thick concrete or lead reduces their intensity, which is why radiotherapy rooms have thick walls.

Neutrons

Neutron radiation

Uncharged particles that do not ionize directly, but their interactions produce alpha, beta, gamma or X-rays that do. They are stopped only by thick concrete, water or paraffin, and are produced in reactors and accelerators.

Electron capture

Electron capture

A K-shell electron is pulled into the nucleus, combines with a proton to form a neutron, and a neutrino is released. The atomic number decreases by 1 while the mass number is unchanged. It helps isotopes reach a more stable state and is used in some diagnostic imaging isotopes.

p+ + e− → n + νe

Half-life in radioactive decay

Half-life in radioactive decay
−dN/dt = λN  |  N(t) = N0e−λt  |  t1/2 = ln2/λ = 0.693/λ  |  τ = 1/λ ≈ 1.44 t1/2

The half-life is the time for half the radioactive nuclei to decay. Mean life (τ) is the average lifetime of a single nucleus. After n half-lives, N = N0(1/2)n.

Half-lives (n)012345
Remaining100%50%25%12.5%6.25%3.125%
Decayed0%50%75%87.5%93.75%96.875%
IsotopeHalf-lifeRadiationApplication
Technetium-99m6.01 hoursGamma (140 keV)Diagnostic SPECT (bone, renal, cardiac)
Iodine-1318.02 daysBeta and gammaThyroid cancer and hyperthyroidism therapy
Carbon-145,730 yearsBetaRadiocarbon dating
Uranium-2384.47 × 109 yearsAlpha seriesGeological dating
Example 1: Tc-99m, 800 MBq, after 12 h (t1/2 = 6 h): n = 2, so A = 800 × 1/4 = 200 MBq.
Example 2: Iodine-131 decay constant: λ = 0.693 / 8.02 ≈ 0.0864 day−1.

Activity and specific activity

Activity and specific activity

Activity (A) is the number of disintegrations per second: A = λN. The SI unit is the becquerel (1 Bq = 1 decay/s). The traditional unit is the curie (1 Ci = 3.7 × 1010 Bq).

Specific activity (SA) is activity per unit mass: SA = A/m, in Bq/g or Ci/g. For a pure radionuclide, SA = λNA/M.

Two samples each have 1000 Bq. Sample A (10 g) has SA = 100 Bq/g and Sample B (100 g) has SA = 10 Bq/g. Same activity, but A is 10 times more concentrated.

Activity falls continuously with decay. Shorter half-lives give higher specific activity, which is preferred in radiopharmaceuticals so targeted radiation is delivered with minimal chemical mass.

Structure of the atom

Matter is anything with mass that occupies space (solid, liquid, gas, plasma). Diagnostic imaging depends on how radiation interacts with matter: an X-ray beam may be transmitted, scattered or absorbed.

An element is a pure substance whose atoms all have the same number of protons (atomic number Z). Hydrogen 1, Carbon 6, Oxygen 8, Aluminium 13, Tungsten 74. Changing neutrons gives a different isotope; changing electrons gives an ion.

Structure of an atom

An atom is the smallest unit of an element that keeps its chemical identity: a tiny nucleus (protons and neutrons) surrounded by an electron cloud. The atomic radius is about 10−10 m and the nucleus about 10−15 to 10−14 m, so most of the atom's volume is not occupied by the nucleus. The nucleus holds almost all the mass.

FeatureAtomMolecule
MeaningUnit of a chemical elementTwo or more chemically bonded atoms
ExampleOne oxygen atom, OO2, H2O, CO2
IdentityDetermined by proton numberDetermined by types and arrangement of atoms
How matter, atoms, elements and molecules are related

Why radiology students study atomic structure

Diagnostic X-ray tube
Scintigraphy: tracer, gamma camera, collimator, detector, image
Scintigraphy: a radioactive tracer (usually Tc-99m, 140 keV gamma) is injected and concentrates in the target organ. A gamma camera captures photons through a collimator onto an NaI(Tl) crystal, which converts them to light. Photomultiplier tubes turn the light into electrical signals and a computer builds the image.

Subatomic particles

Subatomic particles
PropertyProtonNeutronElectron
Symbolp+n0e−
Relative charge+10−1
Charge (C)+1.602 × 10−190−1.602 × 10−19
Mass (kg)1.673 × 10−271.675 × 10−279.109 × 10−31
Mass (u)1.00731.00870.00055
LocationNucleusNucleusElectron cloud
RoleDefines elementMass and nuclear stabilityChemistry and atomic transitions

A proton is about 1836 times heavier than an electron. The nucleus is held together by the strong nuclear interaction, which overcomes the electrostatic repulsion between protons. An atom is neutral when protons equal electrons; losing electrons makes a positive ion (cation), gaining electrons makes a negative ion (anion).

Discoveries: J. J. Thomson measured the electron's charge-to-mass ratio in 1897; Millikan's oil-drop experiment measured the elementary charge; James Chadwick discovered the neutron in 1932.

Atomic number, mass number and neutrons

Atomic number and mass number
Z = protons  |  A = Z + N  |  N = A − Z  |  electrons = Z (neutral)
SpeciesProtonsNeutronsElectrons
Carbon-12666
Sodium-23111211
Na+ (Z=11, A=23)111210
Bromine-80354535
S2− (Z=16, A=32)161618
Common exam mistakes: using electrons to identify the element of an ion; calculating N as Z − A; confusing mass number with the decimal atomic mass; forgetting a 2+ ion has lost two electrons.

Atomic models

Thomson plum pudding model
Rutherford scattering experiment
Bohr atomic model
ModelMain contributionMajor limitation
Dalton (1808)Atomic theory of matterAtoms treated as indivisible; no subatomic particles or isotopes
Thomson (1904)Electrons embedded in a positive sphereCould not explain Rutherford scattering
Rutherford (1911)Compact, positive nucleusCould not explain stability or discrete spectra
BohrQuantized energy levelsFails for multi-electron atoms; replaced by quantum mechanics

In Rutherford's gold-foil experiment most alpha particles passed straight through, some deflected slightly, and a tiny fraction bounced back. This showed that an atom is mostly empty space with its positive charge and mass concentrated in a tiny nucleus. Bohr's model explained the spectral lines of hydrogen using Ephoton = Ehigher − Elower.

Electron shells, binding energy and ionization

Electron shells and binding energy

Shells are named K, L, M, N (n = 1, 2, 3, 4) and hold at most 2n2 electrons: 2, 8, 18, 32. Subshells s, p, d, f hold 2, 6, 10, 14 electrons. Examples: H 1s1, He 1s2, C 1s22s22p2, O 1s22s22p4.

Binding energy is the energy needed to remove an electron completely. Inner-shell electrons are closest to the nucleus, so they have the highest binding energy.

FeatureExcitationIonization
What happensElectron moves to a higher bound stateElectron is completely removed
Energy neededMust match the energy differenceMust equal or exceed binding energy
ResultAtom stays neutralPositive ion and free electron

Isotopes, isobars and isotones

TermMeaningExample
IsotopesSame Z, different ACarbon-12 and Carbon-14
IsobarsSame A, different ZCarbon-14 and Nitrogen-14
IsotonesSame N, different ZCarbon-14 and Nitrogen-15 (N = 8)

Carbon-12 (6 neutrons) and carbon-13 (7) are stable; carbon-14 (8) is radioactive. Stable isotopes do not decay, while radionuclides are unstable and emit radiation. In nuclear medicine, Tc-99m (the "m" means metastable) is used for diagnostic imaging and F-18, a positron emitter, is used for PET scans.

Characteristic X-rays and bremsstrahlung

A characteristic X-ray is produced when an electron fills an inner-shell vacancy:

  1. A high-speed electron strikes a target atom.
  2. An inner-shell electron (for example K) is ejected.
  3. An outer-shell electron fills the vacancy.
  4. The energy difference is emitted as an X-ray photon: E ≈ Binner − Bouter.

Kα is the L to K transition and Kβ is the M to K transition. Example: 20 keV inner and 3 keV outer binding gives a 17 keV photon.

FeatureCharacteristic radiationBremsstrahlung
MechanismShell transition filling an inner vacancyDeceleration of an electron near the nucleus
SpectrumDiscrete linesContinuous
Depends onShell binding energyNuclear charge Z

Formula sheet

FormulaMeaning
Z = protonsAtomic number
A = Z + NMass number
N = A − ZNeutron number
E = hνPhoton energy (h = 6.626 × 10−34 J·s)
c = νλSpeed of light (wavelength and frequency)
C = 2n2Maximum electrons in a shell
Ephoton = Ei − EfTransition energy
A = λN, N = N0(1/2)nActivity and decay
Quick example: a photon of frequency 5.0 × 1014 Hz has E = (6.626 × 10−34)(5.0 × 1014) = 3.313 × 10−19 J ≈ 2.07 eV.
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